Isophthalic acid/P,P-sulfonyldibenzoic acid/ethylene glycol/neopentyl glycol polyester compositions and containers made therefrom

ABSTRACT

Copolyesters having an oxygen permeability of less than 15 cc·mil/100 in. 2  ·day·atm. (at 50% relative humidity and about 73° F.) and a glass transition temperature in excess of 72° C. and having the following four repeating units are contemplated: ##STR1## Based on reactant charges the ratio of (b) units to (a) units will be about 80:20 to about 20:80. Containers made of these polyesters for packaging products of commerce like comestibles are also contemplated.

This is a division, of application Ser. No. 643,283, filed Dec. 22,1975, now U.S. Pat. No. 4,049,631

BACKGROUND OF THE INVENTION

The present application is directed to prescribed polyester compositionsand more specifically to copolyester compositions; additionally, thepresent application is directed to packaging methods and containersfabricated of these polyesters.

Packages, such as bottles, and their method of preparation, made ofpolyethylene terephthalate are disclosed in U.S. Pat. No. 3,733,309.These packages are biaxially oriented bottles and are disclosed to bemanufacturable from a homopolymer of ethylene glycol and terephthalicacid or copolymers of ethylene terephthalate wherein up to 10 molepercent is prepared from the monomer units of for example diethyleneglycol, propane-1,3-diol, butane 1,4 diol, 1,4-hydroxymethylcyclohexane,isophthalic acid, and the like. While bottles from the polyethyleneterephthalate have quite satisfactory permeability characteristics whichallow them to be used for packaging various products of commerceespecially comestible items including foodstuffs, or medicines, theyneed improvement in order to allow them to satisfactorily withstandhigher temperatures. Generally, as indicated above, the permeabilitycharacteristics of polyethylene terephthalate are satisfactory andtypically an unoriented polyethylene terephthalate will have an oxygenpermeability of around 8-10 cc·mil/100 in. ² ·day·atm. and a CO₂permeability of around 48 or 50. The glass transition temperature ofpolyethylene terephthalate, however, is on the order of about 72° C.and, whether a container made therefrom is unoriented or biaxiallyoriented, it will be realized that a higher glass transition temperatureis needed in order to allow a container thereof to withstand highertemperatures. Thus a need exists for a polyester container which iscapable of withstanding higher temperature, for example thoseencountered in an autoclaving procedure and even the temperatures quitefrequently existing in warehouses, than PET.

As will be subsequently seen, the present invention provides containersof prescribed copolyesters which polyesters have glass transitiontemperatures in excess of 72° C. and which have satisfactory oxygenpermeability characteristics thus making them ideally suited for formingoriented or unoriented containers or bottles and for the packaging ofvarious products of commerce; additionally these polyesters have theneeded balance of properties to allow them to be melted and expedientlyformed into containers and the present copolyesters have decompositionpoints which are above normal processing temperatures so as not to causeany significant discoloration problems when synthesizing the compositionand manufacturing bottles and packages therefrom.

While not directed to bottles, U.S. Pat. No. 3,862,084 mentions thehomopolymer of ethylene glycol and terephthalic acid, as well ascopolyesters from terephthalic acid and/or one or more different acids,e.g., isophthalic acid, and from ethylene glycol and/or one or moredifferent alcohols, such as, neopentyl glycol, that is,2,2-dimethyl-1,3-propane diol.

A wide variety of copolyester compositions are known in the prior art.U.S. Pat. No. 3,522,215 discloses a composition formed from terephthalicacid, 1,4-cyclohexane dimethanol and a third, broadly disclosed,dicarboxylic acid (or ester) component which may, for example, bep,p'-sulfonyldibenzoic acid or p,p'-isopropylidenedibenzoic acid; as afourth component, another acid or glycol can be used; the glycolsdisclosed include ethylene glycol, ether glycols, and branched glycolsand carbocyclic glycols with neopentyl glycol (i.e., 2,2-dimethyl1,3-propane diol) being set forth as a branched chain glycol. U.S. Pat.No. 3,547,888 discloses compositions formed from terephthalic acid (orits ester), 1,4-cyclohexane dimethanol and, for example,p,p'-isopropylidenedibenzoic acid (or esters); reference may also be hadto 78 Chemical Abstracts 160332y and German Offenlegungsschrift No.2,146,055.

U.S. Pat. No. 2,744,094 discloses polyesters formed fromp,p'-sulfonyldibenzoic acid (or its esters or acid chloride) plus anaromatic dibasic acid diester, and a polymethylene glycol, and/or analiphatic ether glycol, and indicates that mixtures of straight chainalkane diols or ether glycols may be employed. U.S. Pat. No. 2,744,097discloses polyesters from beta-hydroxyalkyl diesters ofp,p'-sulfonyldibenzoic acid and dihydroxy compounds, for example,aliphatic ether glycols, and polymethylene glycols. U.S. Pat. No.2,744,088 discloses polyesters of p,p'-sulfonyldibenzoic acid (or estersor acid chlorides), an aliphatic straight-chain dibasic acid, or esterthereof, and an alkylene glycol and/or aliphatic ether glycol; branchedchain glycols are mentioned and ethylene glycol and neopentyl glycol(2,2 dimethyl-propane diol-1,3) are specifically set forth. Theforegoing patents are discussed in Vol. 50, Chemical Abstracts, col.16183 and other polyesters from p,p'-sulfonyldibenzoic acid arediscussed in cols. 16180-16182.

U.S. Pat. No. 2,901,466, somewhat similar to some of the above patents,discloses linear polyesters formed from 1,4-cyclohexanedimethanol andone or more hexacarbocyclic dicarboxylic acids (or its ester or halide),e.g., p,p'-sulfonyldibenzoic acid, isophthalic acid, terephthalic acid;modifying glycols, e.g., ethylene glycol, ether glycols, neopentylglycol (2,2'-dimethyl-1,3-propanediol), and carbocyclic glycols are alsoindicated.

German Offenlegungsschrift No. 2,140,615 and Chemical Abstracts, Vol. 78148445e describe a linear polyester having a glass transitiontemperature of about 145° to about 163° C. which is made from ethyleneglycol, neopentyl glycol (2,2'-dimethyl 1,3-propanediol) and bis(4-butoxycarbonylphenyl) sulfone (butyl ester of p,p'-sulfonyldibenzoicacid).

Recently issued U.S. Pat. No. 3,890,256 discloses polyesters formed fromneopentyl glycol but indicates that, for its purposes of producing highimpact and high tensile strength, such a glycol is unsatisfactory.

British specification No. 962,913, and its addition Pat. No. 1,044,015,and French Brevet No. 1,456,345 disclose linear polyesters, optionallyalong with another glycol formed from 2,2 4,4-tetramethyl1,3-cyclobutane diol. Polyester forming acid reactants includeterephthalic acid, isophthalic acid, and p,p'-sulfonyldibenzoic acid.Ethylene glycol and neopentyl glycol, as possible modifying alcohols,are indicated in all three documents.

Thus, as will be seen from the foregoing, an extensive amount of workhas been done with polyesters but little has been done to satisfy theneeds of the packaging industry for an improved polyester containercomposition suitable for the packaging of various products, especiallycomestibles like foodstuffs or medicines, and the like. That is, no onehas focused their attention on satisfying the need for providing apackaging container of a linear polyester having satisfactory oxygenpermeability characteristics and a glass transition temperature higherthan polyethylene terephthalate.

Thus in accordance with the present invention there is provided animproved polyester which can be melted and molded to a clear containerfor use in the packaging industry wherein the repeating units of thepolyester, or the radicals remaining after transesterification, oresterification, and polycondensation consists essentially of (a), (b),(c), and (d) wherein

    ______________________________________                                                   ##STR2##                                                           and                                                                                      ##STR3##                                                           and       (c) is OCH.sub.2CH.sub.2O                                           and       (d) is OCH.sub.2C(CH.sub.3).sub.2CH.sub.2O.                         ______________________________________                                    

The polyesters contemplated herein have an oxygen permeability asmeasured by ASTM D-1434-66 of less than 15 cc·mil/100 in.² ·day·atm. anda glass transition temperature in excess of about 72° C. The mole ratio,based on the amounts of the reactants, i.e., the polyester formingprecursor, used in the reaction, of the (b) units above to the (a) unitsabove will be between about 80:20 and about 20:80 and the ratio of the(c) units above to (d) units above will be about 80:20. Generally theprecursors of the (a) and (b) units as well as the (d) and (c) unitsreact to form the polyesters in about the molar proportion used in thesynthesis of the polyester.

The polyesters contemplated herein, and perhaps more accuratelycopolyesters, are the polyester products wherein units (a), indicatedabove, are obtained from a polyester forming precursor which isp,p'-sulfonyldibenzoic acid, esters thereof, or acid halides thereof,and wherein the (b) units indicated above are obtained from isophthalicacid, esters or acid halides thereof. Units (c) and (d) above arerespectively obtained from polyester forming precursors which areethylene glycol and neopentyl glycol (2,2-dimethyl -1,3-propanediol).

In an especially desirable embodiment the ratio of (b) units to (a)units in the polyester, based on reaction proportions, will be betweenabout 60:40 and about 20:80 with the ratio, based on reactantproportions, of (c) units to (d) units being about 80:20.

The esters contemplated above as the polyester forming precursor may beany of the well known esters, e.g., aliphatic esters, or aromaticesters. Preferred aliphatic, or acyclic, esters are the alkyl estershaving from 1 to about 4 carbon atoms with the methyl or ethyl esterbeing especially preferred. The phenyl esters are preferred aromaticesters. Instead of using the acid or esters, acid halides may likewisebe employed with the acid chloride being quite suitable. Thus forexample units (a) may be the polymerization radical obtained fromp,p'-sulfonyldibenzoyldichloride and units (b) the polymerizationradical obtained from isophthaloyldichloride.

The polyesters as contemplated herein may be synthesized by methodsgenerally known in the art for producing polyesters wherein at least onepolyester-forming dicarboxylic acid, ester, or halides thereof, isreactively combined with at least stoichiometric amounts of at least onepolyester-forming dibasic alcohol under conditions of temperaturepressure and catalysis as to form the polyester. In the usual procedurethe method of reactively combining the acid, acid ester, or acid halidewith the dibasic alcohol is a two-step process involving atransesterification step, or esterification step depending on thestarting materials, followed by a polycondensation step with thereaction being done in a melt condition. Temperatures employed whichwill be quite suitable for forming the present polyesters will bebetween about 200° or 210° C. up to about 300° C. or so. Additionally inthe usual procedure a stoichiometric excess of glycol with be employed,with the mole ratio of ethylene glycol to neopentyl glycol being about80:20. Generally the amount will be between about 2 to about 3 moles oftotal glycol per mole of total dicarboxylic acid, or ester or halide,employed with a quite convenient amount being about 2.5 moles.

Conventional catalysts are likewise employed. For exampletransesterification is effected in the presence of effective catalyticamounts of transition metal compounds, alkaline earth metal compounds,or alkali metal compounds, for example the acetates, oxides, phenoxides,and alkoxides. Specific suitable catalysts will be, for example, zincacetate, manganese acetate, magnesium acetate and calcium acetate, andtitanium alkoxides like titanium tetrabutoxides. Suitablepolycondensation catalysts include for example antimony acetate,antimony trioxide, titanium alkoxide, and organotinoxides, for examplestannous alkoxides. Usually the catalysts will be present in an amountof about 10⁻⁵ to about 10⁻³ moles of catalysts per mole of total acid,ester or halide employed. In performing the reaction the reactantproportions of course will be selected as indicated previously.Additionally as previously indicated units (a) and (b) of the polyesterare, relative to themselves, present in about the same ratio as that oftheir precursors in the reaction charge. Similarly the ratio of (d) to(c) units will be about the same as the molar ratio used in the reactionfor their precursors.

The present invention also contemplates an improvement in methods ofpackaging products wherein a product is placed into a polyestercontainer by employing the polyesters described herein as the polyestersfrom which the container is formed. Thus for example all that isrequired is to form an appropriate container of the polyesterscontemplated herein and then using that container to package foodstuffs,beverages, medicines, and the like.

The present polyesters can be melt molded into containers, for examplebottles, and these containers will be clear, i.e., to the unaided eyethe container will be transparent thereby allowing for the visualobservation of the packaged product through the container walls. Inpassing it should be mentioned that when the term melt-molded isemployed herein this contemplates conventional known processes whereinthermoplastic materials, for example polyethylene terephthalate, arefirst taken to a melt state and then molded for example by blow moldingtechniques, or injection molding techniques, or combinations thereof,into a final container or bottle. Thus for example the presentpolyesters can be melt molded into bottles or jars by techniqueswherein, for example, a parison is first formed by a blow molding orinjection molding operation and wherein the parison is biaxiallystretched or oriented and formed into a final configuration, again forexample, by blow molding. Thus copolyesters as contemplated in thepresent invention may be melt molded to clear bottles and containers foruse in the packaging industry using any of the techniques known in theart for forming melt molded containers.

While the foregoing describes the present invention with sufficientparticularity to enable those skilled in the art to make and use samethere nonetheless follows, for exemplary purposes only, a few specificexamples.

EXAMPLE I

A polyester was prepared having the following repeating units in itsbackbone.

    ______________________________________                                         ##STR4##                                                                      ##STR5##                                                                     (c) OCH.sub.2CH.sub.2O                                                        (d) OCH.sub.2C(CH.sub.3).sub.2CH.sub.2O                                       ______________________________________                                    

Based on the proportions of the polyester forming precursors used in thereaction the mole ratio of (b):(a) was about 60:40 and the mole ratio of(c):(d) was 80:20. The specific charge of ingredients, or precursors,was about 0.0309 moles of dimethyl sulfonyldibenzoate (DMS), about0.0463 moles of dimethyl isophthalate (DMI), about 0.154 moles ofethylene glycol (EG), and about 0.038 moles of neopentyl glycol (NPG).For catalytic purposes the charge also included about 3.86 × 10⁻⁵ molesof Zn(C₂ H₃ O₂)₂.2H₂ O and about 1.46 × 10⁻⁵ moles of Sb₂ O₃.

The mixture of the starting materials were weighed into a 300 ml,three-necked round bottom flask equipped with a stirrer, nitrogen inlettube, and a condenser. The contents of the flask were heated at about195° to about 205° C. for 3 hours with nitrogen flowing into thereaction flask to provide a nitrogen blanket. About 80% of thetheoretical methanol by-product was removed. After this three hourperiod at 105° to 205° C. the contents were then heated to about 260° C.and a vacuum of about 24 mm Hg was applied and the system held for about1 hour. Ethylene glycol, neopentyl glycol, and by-product methanol wasremoved. The condensation of the prepolymer polyester was then continuedat a temperature of about 285° to about 295° C. and was maintained therefor a period of about 3-4 hours under a vacuum of about 0.5 millimetersof mercury. During this time excess ethylene glycol and neopentyl glycolwas further removed by distillation. After this period the polymer wasremoved and found to have a glass transition temperature, as measuredwith a Differential Scanning Calorimeter, of about 93° C., and an oxygenpermeability, as measured by ASTM D-1434-66, of about 11.2 cc·mil/100in.² ·day·atm. at about 73° F. and 50% relative humidity and a CO₂permeability of about 40.6 cc·mil/100 in.² ·day·atm. The polymer waseasily formed into flexible clear films.

Following the known forming procedures of the prior art, e.g., U.S. Pat.No. 3,733,309, a biaxially oriented container (i.e., a container havinga bottom wall and a circumferential sidewall merging with and proceedingupwardly from the bottom wall, the sidewall at its upper margin taperinginwardly and merging with a neck portion defining a mouth opening) isformed from the above-produced polymer. This container is clear and uponbeing filled by placing foodstuffs, beverages, medicines and the liketherein and closing the container shows excellent characteristics forpackaging of such products. A similar bottle, but one which is notoriented also shows excellent characteristics for packaging but isweaker.

EXAMPLES II and III

Following the procedure of Example I two polyesters were prepared. Themole ratio of DMI to DMS in the reactant charge was 30:70 for onepolyester and 20:80 for the other. In both cases the reactant chargemole ratio of EG to NPG was about 80:20. The former polyester had anoxygen peremeability of 10.2, a carbon dioxide permeability of 72.2, aglass transition temperature of 117° C. and an inherent viscosity of0.49. The values for the latter polyester were 12.4, 95.0, 127° C. and0.64 respectively. These polyesters are excellent materials for formingtransparent containers for the packaging of foodstuffs, beverages,medicines, and the like.

In a similar manner a polyester was produced using the polyestersynthesis procedure as above but without any dimethyl isophthalate. Thatis the ratio of (c):(d) was about 80:20 and the ratio of (b):(a) was0:100. The polyester had a glass transition temperature of about 137° C.but its permeability characteristics are unsatisfactory (O₂ = 20.3 andCO₂ = 147).

I claim:
 1. In a method of packaging a product comprising placing saidproduct in a polymeric polyester container, the improvement wherein saidpolyester container is a container of a polyester, the repeating unitsof said polyester consisting essentially of ##STR6## said polyesterhaving an oxygen permeability of less than 15 cc·mil/100 in.² ·day·atm.and a glass transition temperature in excess of 72° C., said (a) and (b)units and said (c) and (d) units respectively being the units formed byreactively combining polyester forming precursors thereof in an amountof at least one mole of the precursors of said (c) and (d) units permole of precursors of said (a) and (b) units and wherein the precursorsof said units in forming said polyester by said reactive combining arein a molar ratio of said (b) unit precursor to said (a) unit precursorof about 80:20 to about 20:80 and a molar ratio of said (c) unitprecursor to said (d) unit precursor of about 80:20.
 2. In a packagecomprising a polyester container and foodstuffs or medicines enclosed insaid container, the improvement wherein said polyester container is acontainer formed of a polyester, the repeating units of said polyesterconsisting essentially of ##STR7## and (c) --O--CH₂ --CH₂ --O-- and (d)--O--CH₂ --C(CH₃)₂ --CH₂ --O--,said polyester having an oxygenpermeability of less than 15 cc·mil/100 in.² ·day·atm. and a glasstransition temperature in excess of 72° C., said (a) and (b) units andsaid (c) and (d) units respectively being the units formed by reactivelycombining polyester forming precursors thereof in an amount of at leastone mole of the precursors of said (c) and (d) units per mole ofprecursors of said (a) and (b) units and wherein the precursors of saidunits in forming said polyester by said reactive combining are in amolar ratio of said (b) unit precursor to said (a) unit precursor ofabout 80:20 to about 20:80 and a molar ratio of said (c) unit precursorto said (d) unit precursor of about 80:20.
 3. The improvement of claim 1wherein said precursor mole ratio of (b) to (a) units is about 60:40 toabout 20:80, said polyester having an oxygen permeability of less thanabout 12.4 and a glass transition temperature between about 93° C. andabout 127° C. and a CO₂ permeability of less than about
 95. 4. Theimprovement of claim 1 wherein said ratio of (b) units to (a) units isabout 30:70 to about 20:80, said polyester having a glass transitiontemperature between about 117° and 127° C. and an oxygen permeabilitybetween about 10.2 and about 12.4.
 5. The improvement of claim 1 whereinsaid container is a clear container.
 6. The improvement of claim 2wherein said precursor mole ratio of (b) to (a) units is about 60:40 toabout 20:80, said polyester having an oxygen permeability of less thanabout 12.4 and a glass transition temperature between about 93° andabout 127° C. and a CO₂ permeability of less than about
 95. 7. Theimprovement of claim 2 wherein said ratio of (b) units to (a) units isabout 30:70 to about 20:80, said polyester having a glass transitiontemperature between about 117° and 127° C. and an oxygen permeabilitybetween about 10.2 and about 12.4.
 8. The improvement of claim 2 whereinsaid container is a clear container.